Below are the recommended email server settings (SMTP mail server) for
Windows Live users
Outlook.com Server Setup
In Method, click your Profile icon in the upper-right and then click Account Settings.
Scroll down until you find Connection. Select it to go to its settings.
Within the Email delivery provider, uncheck the checkbox to Use Method's server to deliver emails for you (recommended).
Fill in the fields as shown:
There is one further step you must do:
Unblock Method's IP Address within your Microsoft Account
Click Test and wait for on-screen confirmation.